How Cadmium yellow/red is made:
Origin: artificial | Minerals: greenockite and hawleyite (at Mineralogy Database). Those natural minerals though known in nature were not used for pigments. |
greenockite (CdS) |
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Artificial variety of pigment | Precipitation of a solution of cadmium(II)-nitrate with a solution of sodium sulfide. |
In the lab | |
Materials needed: | Cadmium(II)-nitrate (Cd(NO3)2 · 4 H2O), Sodium sulfide (Na2S · 9 H2O) |
Safety (MSDSs): | Cadmium(II)-nitrate, Sodium sulfide (at Fisher Scientific) |
Method: | Solution of 9,7 g Cd(NO3)2 · 4 H2O in 50 ml deionized water is added slowly to a stirred solution of 8,3 g Na2S · 9 H2O in 50 ml deionized water. The resulting precipitate is filtered, dried and homogenized in a mortar. |