Titanium white

/ tie • tay • nee • uhm   wite /

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About the chemical structure:

Chemical name: Titanium dioxide
Formula: TiO2
3D model:


Crystal structure of anatase

Crystal structure of rutile

grey = titanium, red = oxygen

Crystal system: Anatase: Tetragonal - Ditetragonal Dipyramidal (at Mineralogy Database)
Refractive index: anatase: 2.3 - 2.65

Color:

Color Index (C.I.) PW 6

How can you identify Titanium white?

Imaging:

UVF: no

OM: Microcrystalline in nature with fine particles. Very fine pseudo-opaque but generally colour less crystals. Often rounded rhomboids. The crystals are so small that they often appear cream to a light brown opaque colour under normal incident light on the microscope. Particles are usually up to 1μm in size.

Microscopic appearance at x500 mag

Analytics:

It's identified by means of FTIR and Raman.

Raman spectra: ColoRaman

FTIR spectra: IRUG

 

 

Usage and handling:

Permanence: Toxicity:

Lightfast: excellent.

Degradation processes: unaffected by dilute alkali's, acids, light and air. Non-reactive with drying oils and therefore has avery slow drying time. High oil absorbing nature.

Non toxic.

MSDS: Kremer

Literature:

Artists’ Pigments. A Handbook of Their History and Characteristics, Vol. 3: E.W. Fitzhugh (Ed.) Oxford University Press 1997, p. 295-355

Philippe Colomban, Gerard Sagon and Xavier Faurel, Differentiation of antique ceramics from the Raman spectra of their coloured glazes and paintings, J. Raman Spectrosc. 2001; 32: 351–360.

 Sections:  

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  blues  

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  yellows  

  oranges  

  reds  

  whites  

  browns  

  blacks