Pigments through the Ages

              
/ vird • uh • gree /
Verdigris 
 
   

     
 

  1.  Overview  
  2. History
of use
 
  3. Making the
pigment
 
  4. Technical
details
 
  
  About the chemical structure:
        
Chemical name:
Copper acetates ranging in color from green to blue. Neutral verdigris is Cu(CH3COO)2· H2O, and basic verdigris contains more Cu(OH)2 and H2O.
Formula:
Cu(OH)2 · (CH3COO)2 · 5 H2O
Refractive index:
alpha = 1.53; gamma = 1.56
A swatch of Verdigris paint:
  

  How can you identify Verdigris?
        
Chemical identification:
n/a

Spectra:
Raman spectra: neutral verdigris, basic verdigris and hydrated basic verdigris (at University College London)


  Usage and handling:
        
Permanence:
Toxicity:
good lightfastness
MSDS (at Fisher Scientific)

  Literature:   
        
Kühn, H., Grünspan und seine Verwendung in der Malerei, Farbe und Lack, 70, 1964, p. 703-711

Schweizer, F. und Mühletaler, B. Einige Grüne und Blaue Kupferpigmente, Farbe und Lack, 74 1968, p. 1159-73

Artists’ Pigments. A Handbook of Their History and Characteristics, Vol. 2: A. Roy (Ed.) Oxford University Press 1993, p. 131-147


Other greens        
(intro) - Cobalt green - copper resinate - Emerald green - Green earth - malachite      
verdigris - viridian        

 Sections:  

  purples  

  blues  

  greens  

  yellows  

  oranges  

  reds  

  whites  

  browns  

  blacks  

    
 Look for:    
webexhibits.org/pigments   -   Credits & Feedback  -   Bibliography